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• W2070981567 abstract "Abstract A new class of ionophore consisting of two calix[4]arene units linked through the lower rim by two ethylene chains, in combination with propyl ether and phenolic functional groups, has been developed. These calix[4]semitube molecules exhibit remarkable selectivity and fast complexation kinetics for potassium over all Group 1 metal cations. Molecular modelling studies, using structural models derived from crystallographic data, suggest the potassium cation is complexed by a horizontal, side‐on route and not through the calix[4]arene annulus. The length of the bridging alkylene chain between the respective calix[4]arenes of the semitube structure dictates the strength and selectivity of alkali metal cation binding." @default.
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• W2070981567 date "2003-05-21" @default.
• W2070981567 modified "2023-10-11" @default.
• W2070981567 title "Potassium Selective Calix[4]semitubes" @default.
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• W2070981567 doi "https://doi.org/10.1002/chem.200204518" @default.
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