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• W2070989843 abstract "The stable and metastable melting relations for silicon in the diamond and Si136 clathrate-II structures at positive and negative pressures are calculated by molecular dynamics computer simulation. The simulated liquid and crystalline clathrates undergo cavitation at approximately -3 and -12 GPa. Between these limits a stretched crystal would transform directly to gas in response to a mechanical instability. Most importantly, the clathrate-II crystal becomes thermodynamically stable over the diamond at negative pressure below -1 GPa at the melting point. Si136 should then crystallize from a slightly stretched liquid, which would have the same volume as a diamond-structure crystal." @default.
• W2070989843 created "2016-06-24" @default.
• W2070989843 creator A5005917049 @default.
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• W2070989843 date "2003-04-04" @default.
• W2070989843 modified "2023-10-18" @default.
• W2070989843 title "Crystal-Liquid Phase Relations in Silicon at Negative Pressure" @default.
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• W2070989843 doi "https://doi.org/10.1103/physrevlett.90.135703" @default.
• W2070989843 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/12689309" @default.
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