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• W2071004954 abstract "Framework Ti-substituted, three-dimensional, mesoporous titanosilicates, Ti-SBA-12 and Ti-SBA-16, were prepared by direct hydrothermal synthesis method. These catalysts showed catalytic activity higher than the hitherto known titanosilicates for the oxidation of cyclic olefins (cyclohexene and cyclooctene) with tert.-butyl hydroperoxide. An epoxide selectivity of 100% and olefin conversion greater than 92% were obtained. Cubic Ti-SBA-16 with interconnected cage-like mesopore structure was more active than hexagonal Ti-SBA-12. X-ray diffraction and diffuse reflectance UV–vis, Fourier transform infrared, Raman and electron paramagnetic resonance spectroscopies provided evidence for the substitution of Ti4+ (for Si4+) in the framework locations. The catalytic activity correlated with the concentration of framework-substituted, tetrahedral Ti4+ ions. Easy accessibility of the active sites and the three-dimensional mesoporous structure are the possible causes for the superior activity of these titanosilicate catalysts." @default.
• W2071004954 created "2016-06-24" @default.
• W2071004954 creator A5021269346 @default.
• W2071004954 creator A5028331487 @default.
• W2071004954 date "2012-12-01" @default.
• W2071004954 modified "2023-09-25" @default.
• W2071004954 title "Selective oxidation of cyclic olefins over framework Ti-substituted, three-dimensional, mesoporous Ti-SBA-12 and Ti-SBA-16 molecular sieves" @default.
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• W2071004954 doi "https://doi.org/10.1016/j.cattod.2012.01.035" @default.
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