FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2071007213> ?p ?o ?g. }

• W2071007213 endingPage "15752" @default.
• W2071007213 startingPage "15743" @default.
• W2071007213 abstract "TiO(2) nanoparticles have been widely utilized in photocatalysis, but the atomic level understanding on their working mechanism falls much short of expectations. In particular, the correlation between the particle structure and the photocatalytic activity is not established yet, although it was observed that the activity is sensitive to the particle size and shape. This work, by investigating a series of TiO(2) anatase nanoparticles with different size and shape as the photocatalyst for water oxidation, correlates quantitatively the particle size and shape with the photocatalytic activity of the oxygen evolution reaction (OER). Extensive density functional theory (DFT) calculations combined with the periodic continuum solvation model have been utilized to compute the electronic structure of nanoparticles in aqueous solution and provide the reaction energetics for the key elementary reaction. We demonstrate that the equilibrium shape of nanoparticle is sensitive to its size from 1 to 30 nm, and the sharp crystals possess much higher activity than the flat crystals in OER, which in combination lead to the morphology dependence of photocatalytic activity. The conventionally regarded quantum size effect is excluded as the major cause. The physical origin for the shape-activity relationship is identified to be the unique spatial separation/localization of the frontier orbitals in the sharp nanoparticles, which benefits the adsorption of the key reaction intermediate (i.e., OH) in OER on the exposed five-coordinated Ti of {101} facet. The theoretical results here provide a firm basis for maximizing photocatalytic activity via nanostructure engineering and are also of significance for understanding photocatalysis on nanomaterials in general." @default.
• W2071007213 created "2016-06-24" @default.
• W2071007213 creator A5023502514 @default.
• W2071007213 creator A5091396785 @default.
• W2071007213 date "2011-09-09" @default.
• W2071007213 modified "2023-10-16" @default.
• W2071007213 title "Particle Size, Shape and Activity for Photocatalysis on Titania Anatase Nanoparticles in Aqueous Surroundings" @default.
• W2071007213 cites W1965309006 @default.
• W2071007213 cites W1966673120 @default.
• W2071007213 cites W1967536551 @default.
• W2071007213 cites W1972370403 @default.
• W2071007213 cites W1973344553 @default.
• W2071007213 cites W1978383254 @default.
• W2071007213 cites W1979035361 @default.
• W2071007213 cites W1981368803 @default.
• W2071007213 cites W1982571974 @default.
• W2071007213 cites W1982677496 @default.
• W2071007213 cites W1999046538 @default.
• W2071007213 cites W2001242965 @default.
• W2071007213 cites W2013762068 @default.
• W2071007213 cites W2017128337 @default.
• W2071007213 cites W2022074888 @default.
• W2071007213 cites W2022112942 @default.
• W2071007213 cites W2023166289 @default.
• W2071007213 cites W2023463298 @default.
• W2071007213 cites W2023899112 @default.
• W2071007213 cites W2027232636 @default.
• W2071007213 cites W2033803368 @default.
• W2071007213 cites W2034888609 @default.
• W2071007213 cites W2042492216 @default.
• W2071007213 cites W2045596260 @default.
• W2071007213 cites W2056300247 @default.
• W2071007213 cites W2061535118 @default.
• W2071007213 cites W2061645716 @default.
• W2071007213 cites W2067232009 @default.
• W2071007213 cites W2075385768 @default.
• W2071007213 cites W2077819780 @default.
• W2071007213 cites W2079378606 @default.
• W2071007213 cites W2085719895 @default.
• W2071007213 cites W2087697908 @default.
• W2071007213 cites W2091778382 @default.
• W2071007213 cites W2093031590 @default.
• W2071007213 cites W2093065511 @default.
• W2071007213 cites W2093817514 @default.
• W2071007213 cites W2111062994 @default.
• W2071007213 cites W2312412478 @default.
• W2071007213 cites W2326689924 @default.
• W2071007213 cites W2333598814 @default.
• W2071007213 cites W2394736827 @default.
• W2071007213 cites W2523231883 @default.
• W2071007213 cites W312464463 @default.
• W2071007213 cites W4241456496 @default.
• W2071007213 cites W4246568879 @default.
• W2071007213 doi "https://doi.org/10.1021/ja206153v" @default.
• W2071007213 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/21879719" @default.
• W2071007213 hasPublicationYear "2011" @default.
• W2071007213 type Work @default.
• W2071007213 sameAs 2071007213 @default.
• W2071007213 citedByCount "260" @default.
• W2071007213 countsByYear W20710072132012 @default.
• W2071007213 countsByYear W20710072132013 @default.
• W2071007213 countsByYear W20710072132014 @default.
• W2071007213 countsByYear W20710072132015 @default.
• W2071007213 countsByYear W20710072132016 @default.
• W2071007213 countsByYear W20710072132017 @default.
• W2071007213 countsByYear W20710072132018 @default.
• W2071007213 countsByYear W20710072132019 @default.
• W2071007213 countsByYear W20710072132020 @default.
• W2071007213 countsByYear W20710072132021 @default.
• W2071007213 countsByYear W20710072132022 @default.
• W2071007213 countsByYear W20710072132023 @default.
• W2071007213 crossrefType "journal-article" @default.
• W2071007213 hasAuthorship W2071007213A5023502514 @default.
• W2071007213 hasAuthorship W2071007213A5091396785 @default.
• W2071007213 hasConcept C127413603 @default.
• W2071007213 hasConcept C147597530 @default.
• W2071007213 hasConcept C147789679 @default.
• W2071007213 hasConcept C152365726 @default.
• W2071007213 hasConcept C155672457 @default.
• W2071007213 hasConcept C159467904 @default.
• W2071007213 hasConcept C161790260 @default.
• W2071007213 hasConcept C171250308 @default.
• W2071007213 hasConcept C178790620 @default.
• W2071007213 hasConcept C184651966 @default.
• W2071007213 hasConcept C185592680 @default.
• W2071007213 hasConcept C186187911 @default.
• W2071007213 hasConcept C187530423 @default.
• W2071007213 hasConcept C192562407 @default.
• W2071007213 hasConcept C2777402863 @default.
• W2071007213 hasConcept C42360764 @default.
• W2071007213 hasConcept C65165184 @default.
• W2071007213 hasConceptScore W2071007213C127413603 @default.
• W2071007213 hasConceptScore W2071007213C147597530 @default.
• W2071007213 hasConceptScore W2071007213C147789679 @default.
• W2071007213 hasConceptScore W2071007213C152365726 @default.
• W2071007213 hasConceptScore W2071007213C155672457 @default.
• W2071007213 hasConceptScore W2071007213C159467904 @default.
• W2071007213 hasConceptScore W2071007213C161790260 @default.

• next