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- W2071013117 abstract "Coexistence curves for the quasi-ternary system of water + n-decane + n-undecane + tert-butanol have been determined by measurements of the refractive index in three coexisting liquid phases. The binary mixtures of n-decane + n-undecane constructed the quasi-pure components in which the mass fraction beta of n-decane controls the approach to the tricritical point. The coexistence curves can be fitted to Scott's extended theory and can be extrapolated to a tricritical point at (44.1 +/- 0.3) degrees C and beta = 0.77 +/- 0.02 corresponding to an average n-alkane-carbon number of 10.19 +/- 0.02. The nonclassical critical amplitude ratio has been confirmed to be 4-5% smaller than the classical value, which is consistent with Fisher's prediction." @default.
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- W2071013117 date "2006-02-23" @default.
- W2071013117 modified "2023-10-18" @default.
- W2071013117 title "Tricritical Phenomena in Quasi-ternary Mixtures of Water + <i>n</i>-Decane + <i>n-</i>Undecane + <i>tert</i>-Butanol" @default.
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- W2071013117 doi "https://doi.org/10.1021/jp0560415" @default.
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