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- W2071014259 abstract "The title compound (H2L), C27H28N4O2, is an asymmetric binucleating ligand with well defined soft (N3O-donor) and hard (NO2-donor) sides. H2L was designed as a ligand for the preparation of heterodinuclear mixed-valence MIII/M′II complexes which are models for heterobimetallic active sites of enzymes, principally calcineurin. The molecular structure of H2L shows a spatial pre-organization of the donor groups for coordination. This conformation is stabilized by bifurcated intra- and intermolecular O—H⋯N hydrogen bonds involving both phenol groups. The intermolecular hydrogen bonds link molecules of H2L into chains running parallel to the crystallographic c axis." @default.
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- W2071014259 date "2007-01-13" @default.
- W2071014259 modified "2023-09-24" @default.
- W2071014259 title "2-{[Bis(2-pyridylmethyl)amino]methyl}-6-[(2-hydroxyanilino)methyl]-4-methylphenol: a novel binucleating asymmetric ligand as a precursor to synthetic models for metalloenzymes" @default.
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- W2071014259 doi "https://doi.org/10.1107/s0108270106050517" @default.
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