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- W2071014716 abstract "The mechanism of acid-catalyzed hydrocarbon reactions such as skeletal isomerization, hydride transfer, alkylation, dehydrogenation and cracking in superacid media and over solid zeolites is analyzed and compared. In particular, the stability, rearrangements and nature (reaction intermediates or transition states) of trivalent carbenium ions and non-classical pentacoordinated carbonium ions in homogeneous and heterogeneous phase are discussed. It is concluded that both carbenium and carbonium ions may exist as true reaction intermediates in zeolite-catalyzed processes only when the positive charge is not easily accessible to framework oxygen atoms." @default.
- W2071014716 created "2016-06-24" @default.
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- W2071014716 date "2008-03-01" @default.
- W2071014716 modified "2023-10-14" @default.
- W2071014716 title "Are carbenium and carbonium ions reaction intermediates in zeolite-catalyzed reactions?" @default.
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- W2071014716 doi "https://doi.org/10.1016/j.apcata.2007.09.050" @default.
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