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• W2071033132 abstract "The synthesis of aluminophosphates is investigated using a number of triptycene-based organic structure-directing agents (OSDA). These OSDAs are designed to synthesize extra-large pore and/or large cavity-containing molecular sieves. Starting from the hydrophobic triptycene molecule, OSDAs are prepared by introducing three amine-based centers that can be charged either by protonation in the acidic aluminophosphate reaction media or through quaternization. VPI-5 is synthesized using these tripytycene OSDAs, and the OSDAs are occluded inside the pores. This synthesis marks the first time VPI-5 has been made as a single phase with an OSDA occluded inside the framework of the as-made material that is not removed by simple washing with water or other solvents. Additionally, several other aluminophosphates with unknown structures are synthesized using these new OSDAs." @default.
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• W2071033132 date "2015-05-01" @default.
• W2071033132 modified "2023-09-24" @default.
• W2071033132 title "Triptycene structure-directing agents in aluminophosphate synthesis" @default.
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• W2071033132 doi "https://doi.org/10.1016/j.micromeso.2015.01.045" @default.
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