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• W2071048087 abstract "The C7C12 triene fragment of 9-cis-retinoids 8 was stereoselectively generated by treatment of propargylic alcohol 3 with phenylsulfenyl chloride/triethylamine at −78 °C, followed by stereospecific reduction of the resulting vinylsulfoxide (t-BuLi, MeLi, MeOH, −78 °C). Thus, 9-cis-retinoic acid 2, the natural ligand of the retinoid X receptor (RXR) was straightforwardly synthesized from 8 in two steps." @default.
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• W2071048087 date "1998-06-01" @default.
• W2071048087 modified "2023-10-16" @default.
• W2071048087 title "Stereoselective isomerization of 10-arylsulfenate-11,12-dehydroretinoids to 9-cis-retinoids" @default.
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• W2071048087 doi "https://doi.org/10.1016/s0040-4039(98)00810-7" @default.
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