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- W2071052915 abstract "A new Cd(II) complex, [CdL(DMSO)2Cl2] n , L = bis(N-phenylthiourea), has been synthesized and its crystal structure determined from single-crystal diffraction data. The compound is orthorhombic, space group Pna21, with a = 18.728(1), b = 12.2601(8), c = 22.879(1) A, V = 5253.3(6) A3. L acts as an exobidentate neutral ligand and Cd is octahedral, being bonded to two S atoms, two terminal Cl ions and two DMSO solvent molecules. The structure is that of a one-dimensional polymer, with chains running parallel to the b axis. Polymeric chains are stabilized by N–H…Cl hydrogen bonding, while intermolecular S…O contacts connect the chains. Thermal decomposition of the complex starts at 120°C by desolvation and is continuous over the recorded temperature range." @default.
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- W2071052915 date "2006-03-20" @default.
- W2071052915 modified "2023-10-05" @default.
- W2071052915 title "Synthesis and characterisation of a novel polymeric Cd complex, catena-(μ-thio)[bis(N-phenylthiourea] bis(dimethylsulphoxide)dichlorocadmium(II)" @default.
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- W2071052915 doi "https://doi.org/10.1080/00958970500171240" @default.
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