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• W2071062185 startingPage "8030" @default.
• W2071062185 abstract "Forces across polymer melts are poorly understood despite their importance for adhesion and fabricating composite materials. Using an atomic force microscope (AFM), this interaction was measured for poly(dimethyl siloxane) (PDMS). The structure of the polymer at the surface changed during the first approximately 10 h. Afterward, short-range attractive forces were observed with short-chain PDMS (M(w) = 4200 g/mol). Using PDMS with a molecular weight (M(w) = 18 000 g/mol) above the entanglement limit, we measured a monotonically decaying repulsive force, which indicates that a quasi-immobilized layer had formed at the solid surface. Due to the small radius of curvature of the tip, forces could be measured in equilibrium." @default.
• W2071062185 created "2016-06-24" @default.
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• W2071062185 date "2004-08-07" @default.
• W2071062185 modified "2023-10-16" @default.
• W2071062185 title "Equilibrium Interaction of Solid Surfaces across a Polymer Melt" @default.
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• W2071062185 doi "https://doi.org/10.1021/la049010u" @default.
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• W2071062185 hasPublicationYear "2004" @default.
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