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- W2071137581 abstract "The stepwise intramolecular hydroformylation reaction of allyldiphenylphosphine using a monodentate phosphorus diamide based rhodium catalyst has been studied using NMR spectroscopy. Reaction of the rhodium−hydride complex HRhL3CO (L = triethylbiuretphenylphosphorus diamide) with allyldiphenylphosphine results in the formation of HRhL2(allylPPh2)CO. This compound undergoes hydride migration to form a cyclic rhodium−alkyl complex. When carbon monoxide is added to this complex, ligand exchange and CO insertion occur, leading to the formation of the cyclic rhodium−acyl complex Ph2L(CO)2. Addition of hydrogen completes the cycle forming the coordinated hydroformylated allyldiphenylphosphine ligand. The aldehyde-functionalized phosphine ligand is hydrogenated to the corresponding alcohol." @default.
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- W2071137581 date "2001-02-22" @default.
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- W2071137581 title "Intramolecular Hydroformylation of Allyldiphenylphosphine Using a Monodentate Phosphorus Diamide Based Rhodium Catalyst: An NMR Study" @default.
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- W2071137581 doi "https://doi.org/10.1021/om000890r" @default.
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