Matches in SemOpenAlex for { <https://semopenalex.org/work/W2071157905> ?p ?o ?g. }
- W2071157905 endingPage "259" @default.
- W2071157905 startingPage "251" @default.
- W2071157905 abstract "Effect of basicity of porous metal-carboxylates, such as MIL-100(Al), Cu3(BTC)2·(H2O)3, UiO-66 and amino-modified UiO-66 materials (UiO-66-NH2) on their catalytic performance, was studied in the Knoevenagel condensation of benzaldehyde with malononitrile to 2-benzylidenemalononitrile. According to physicochemical studies, the strength of the basic sites for MIL-100(Al), Cu3(BTC)2·(H2O)3, UiO-66 was in the range of 830–839 kJ/mol, while the amount of basic sites decreased in the order MIL-100(Al) > Cu3(BTC)2·(H2O)3 > UiO-66. The insertion of NH2 groups into the UiO-66 framework led to an increase in the strength of basic sites from 839 to 867 kJ/mol. The catalytic activity of metal carboxylates correlated with the amount of basic sites and the strength of the interaction between metal and oxygen in the “M+n–O2− Lewis acid–base” pair, which was estimated from ionic covalent parameters. The activity of the UiO-66-NH2 materials was higher than that of UiO-66." @default.
- W2071157905 created "2016-06-24" @default.
- W2071157905 creator A5010029501 @default.
- W2071157905 creator A5018007279 @default.
- W2071157905 creator A5023276622 @default.
- W2071157905 creator A5035064522 @default.
- W2071157905 creator A5052274244 @default.
- W2071157905 creator A5057112953 @default.
- W2071157905 date "2014-07-01" @default.
- W2071157905 modified "2023-10-18" @default.
- W2071157905 title "Catalytic behavior of metal–organic frameworks in the Knoevenagel condensation reaction" @default.
- W2071157905 cites W1583236421 @default.
- W2071157905 cites W1967465425 @default.
- W2071157905 cites W1967860492 @default.
- W2071157905 cites W1968690756 @default.
- W2071157905 cites W1971152118 @default.
- W2071157905 cites W1974187663 @default.
- W2071157905 cites W1974230931 @default.
- W2071157905 cites W1974404404 @default.
- W2071157905 cites W1983339698 @default.
- W2071157905 cites W1986238480 @default.
- W2071157905 cites W1990388967 @default.
- W2071157905 cites W1990853155 @default.
- W2071157905 cites W1993684485 @default.
- W2071157905 cites W1996313817 @default.
- W2071157905 cites W1998542462 @default.
- W2071157905 cites W1998729061 @default.
- W2071157905 cites W2001033276 @default.
- W2071157905 cites W2004550299 @default.
- W2071157905 cites W2005638989 @default.
- W2071157905 cites W2005693784 @default.
- W2071157905 cites W2006405227 @default.
- W2071157905 cites W2006953965 @default.
- W2071157905 cites W2008249334 @default.
- W2071157905 cites W2008405897 @default.
- W2071157905 cites W2011029017 @default.
- W2071157905 cites W2011727339 @default.
- W2071157905 cites W2014182208 @default.
- W2071157905 cites W2015317116 @default.
- W2071157905 cites W2015774245 @default.
- W2071157905 cites W2016097691 @default.
- W2071157905 cites W2022167379 @default.
- W2071157905 cites W2022485756 @default.
- W2071157905 cites W2022865885 @default.
- W2071157905 cites W2024905546 @default.
- W2071157905 cites W2027329930 @default.
- W2071157905 cites W2030225089 @default.
- W2071157905 cites W2032046856 @default.
- W2071157905 cites W2034676013 @default.
- W2071157905 cites W2034881626 @default.
- W2071157905 cites W2041760002 @default.
- W2071157905 cites W2048246447 @default.
- W2071157905 cites W2049120608 @default.
- W2071157905 cites W2053665123 @default.
- W2071157905 cites W2064047290 @default.
- W2071157905 cites W2065273650 @default.
- W2071157905 cites W2078444809 @default.
- W2071157905 cites W2078889409 @default.
- W2071157905 cites W2080649912 @default.
- W2071157905 cites W2083966793 @default.
- W2071157905 cites W2088612894 @default.
- W2071157905 cites W2092596181 @default.
- W2071157905 cites W2093377894 @default.
- W2071157905 cites W2095552394 @default.
- W2071157905 cites W2102522500 @default.
- W2071157905 cites W2115764422 @default.
- W2071157905 cites W2115960399 @default.
- W2071157905 cites W2123525424 @default.
- W2071157905 cites W2125169274 @default.
- W2071157905 cites W2317566433 @default.
- W2071157905 cites W2320627461 @default.
- W2071157905 cites W2324777999 @default.
- W2071157905 cites W2333547949 @default.
- W2071157905 cites W4211079585 @default.
- W2071157905 cites W4230753488 @default.
- W2071157905 doi "https://doi.org/10.1016/j.jcat.2014.05.018" @default.
- W2071157905 hasPublicationYear "2014" @default.
- W2071157905 type Work @default.
- W2071157905 sameAs 2071157905 @default.
- W2071157905 citedByCount "111" @default.
- W2071157905 countsByYear W20711579052014 @default.
- W2071157905 countsByYear W20711579052015 @default.
- W2071157905 countsByYear W20711579052016 @default.
- W2071157905 countsByYear W20711579052017 @default.
- W2071157905 countsByYear W20711579052018 @default.
- W2071157905 countsByYear W20711579052019 @default.
- W2071157905 countsByYear W20711579052020 @default.
- W2071157905 countsByYear W20711579052021 @default.
- W2071157905 countsByYear W20711579052022 @default.
- W2071157905 countsByYear W20711579052023 @default.
- W2071157905 crossrefType "journal-article" @default.
- W2071157905 hasAuthorship W2071157905A5010029501 @default.
- W2071157905 hasAuthorship W2071157905A5018007279 @default.
- W2071157905 hasAuthorship W2071157905A5023276622 @default.
- W2071157905 hasAuthorship W2071157905A5035064522 @default.
- W2071157905 hasAuthorship W2071157905A5052274244 @default.
- W2071157905 hasAuthorship W2071157905A5057112953 @default.
- W2071157905 hasConcept C150394285 @default.