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- W2071162667 abstract "The formation of the tetrahedral complexes [NiBr3(solvent)]–, NiBr2–4, [NiI3(solvent)]– and NiI2–4 in acetone in the presence of the bromides and iodides of lithium and various quaternary ammonium cations has been investigated. The tri-halogeno species is unaffected by the counter ion but the extent of formation of the tetra-halogeno species is dependent upon the size of the counter ion: the results with lithium are anomalous. The data is interpreted in terms of the presence of the solvent-shared ion pair [NiX4(solvent)R4N]–. An explanation of the lithium results is given. In solutions containing only nickel, bromide and the counter ion, and at Br/Ni mole ratios in excess of 3 the two species equilibrium tri ⇌ tetra is established; when perchlorate is also present at least one octahedral species is always evident." @default.
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- W2071162667 date "1969-01-01" @default.
- W2071162667 modified "2023-09-25" @default.
- W2071162667 title "Effects of cations upon absorption spectra. Part 1.—Tetrahedral bromo and iodo complexes of nickel(II) in acetone" @default.
- W2071162667 doi "https://doi.org/10.1039/tf9696501427" @default.
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