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• W2071214593 abstract "A practical total synthesis of Bengamides B, E, and Z from a common polyol intermediate is described. Consecutive aldol condensations afford a protected polyol thioester side chain suitable for coupling to the Bengamides. A novel chiral phase transfer catalyzed enantioselective alkylation affords the more highly functionalized amino caprolactams required for Bengamides B and Z. Use of the 2-naphthylmethyl ether protecting group, compatible with the boron Lewis acids required for enantioselective aldol condensation, allows direct access to Bengamide B." @default.
• W2071214593 created "2016-06-24" @default.
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• W2071214593 date "2002-05-18" @default.
• W2071214593 modified "2023-10-10" @default.
• W2071214593 title "A Practical Enantioselective Total Synthesis of the Bengamides B, E, and Z" @default.
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• W2071214593 doi "https://doi.org/10.1021/ol026101e" @default.
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