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- W2071234624 abstract "The construction, control and operation of an array of electrodes used to obtain voltammetric information in a wall- jet geometry is described for flow-stream analysis. The array consisted of a ring-disk arrangement, where the ring is composed of eight radially-spaced 1-mm glassy carbon disks. The ring array surrounds a 3-mm glassy carbon disk in the centre, impinged by a perpendicular 0.3-mm inlet diameter jet. Independent electrode control and monitoring were achieved through a computer-based multi-electrode potentiostat, designed to operate with single reference and counter electrodes. The flow cell was characterised through variation of the inlet jet separation from the planar ring-disk array and control of inlet volume flow-rate. Optimum conditions were chosen with stability as the primary criterion. A jet separation of 7.25 mm and a flow-rate of 1.5 cm3 min−1 ensured wall jet behaviour at the central electrode and planar behaviour at the ring array. These conditions were maintained throug hout subsequent experiments which demonstrated the feasibility of utilising the array of electrodes for voltammetric monitoring of simple mixtures of metal ions, with or without prior separation. The potential of this approach for industrial process monitoring is discussed with a view of maximising information recovery and enhancing data reliability." @default.
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- W2071234624 date "1993-02-01" @default.
- W2071234624 modified "2023-09-26" @default.
- W2071234624 title "Voltammetric information from arrays of individually controlled electrodes: their potential for industrial process measurements" @default.
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- W2071234624 doi "https://doi.org/10.1016/0003-2670(93)80150-j" @default.
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