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- W2071247140 abstract "The reactions of CF3O−, CF3O−·H2O and CF3O−·HF with HCl and of CF3O− with H2O have been studied at room temperature in a flowing afterglow instrument. All reactions with HCl proceed at the gas kinetic rate. The reaction of CF3O−with HCl proceeds by fluoride transfer, whereas CF3O−·H2O and CF3O−·HF react with HCl by ligand switching. The Gibbs free energy change of the reaction of CF3O− with H2O has been determined at room temperature as well as the collisional dissociation rate constant of CF3O−·H2O ions." @default.
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- W2071247140 date "2000-10-01" @default.
- W2071247140 modified "2023-09-26" @default.
- W2071247140 title "Gas phase reactions of CF3O− and CF3O−·H2O and their relevance to the detection of stratospheric HCl" @default.
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- W2071247140 doi "https://doi.org/10.1016/s1387-3806(00)00244-x" @default.
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