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- W2071254992 abstract "Various heteropolyacids, including Keggin-type (H3PW12O40), Dawson-type (H6P2W18O62) and Preyssler-type (H14[NaP5W30O110]) phosphotungstic acids, were examined as catalysts for acylation of ethyl pyruvate with acetic anhydride to synthesize ethyl α-acetoxyacrylate in liquid phase. This compound is one of candidate monomers for bio-based polymers bearing high thermal durability and transparency. Catalytic performances correlated to the acid strength, the proton number and the stability of the phosphotungstic acids. Notably, performance of Preyssler-type phosphotungstic acid per unit mole of catalyst was higher than that of Keggin-type." @default.
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- W2071254992 date "2011-04-01" @default.
- W2071254992 modified "2023-09-26" @default.
- W2071254992 title "Influence of structural differences and acidic properties of phosphotungstic acids on their catalytic performance for acylation of pyruvate ester to α-acyloxyacrylate ester" @default.
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- W2071254992 doi "https://doi.org/10.1016/j.cattod.2010.10.047" @default.
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