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• W2071291215 abstract "The stability of natural STI zeolite in saturated steam at high temperatures (defined as hydrothermal stability as well) is first studied. The stability of parent STI (denoted as R-STI) in steam is better than that in air. The NH4+ type STI zeolite possesses the best hydrothermal stability. The structure, composition and adsorption properties of NH4-STI treated in steam from 350 to 750 °C are characterized with X-ray diffraction (XRD), 27Al magic-angle spinning (MAS) nuclear magnetic resonance (NMR), Fourier transform infrared spectroscopy (FT-IR), X-ray fluorescence scattering spectroscopy (XRF), and N2 adsorption and desorption, respectively. High-temperature steam can make aluminum atoms escape from the zeolite framework to become non-framework aluminum. The NH4+ cations in NH4-STI, which can block the pores as well as the non-framework aluminum, can be fully decomposed to get H-STI at 550 °C. The framework SiO2/Al2O3 ratio can enhance from 6.5 to 21.3 though the chemical SiO2/Al2O3 ratio is almost unchanged." @default.
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• W2071291215 date "2012-02-01" @default.
• W2071291215 modified "2023-10-18" @default.
• W2071291215 title "Studies on the hydrothermal stability of natural and modified STI zeolite" @default.
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• W2071291215 doi "https://doi.org/10.1016/j.micromeso.2011.09.009" @default.
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