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• W2071293492 abstract "An efficient Pd catalyst for the O-arylation of ethyl acetohydroximate with aryl chlorides, bromides, and iodides has been developed. Ethyl acetohydroximate serves as an efficient hydroxylamine equivalent for C−O cross-coupling, thereby allowing for the preparation of O-arylhydroxylamines from simple aryl halides. Short reaction times and broad substrate scope, including heteroaryl coupling partners, allow access to O-arylhydroxylamines that would be difficult to prepare in a single step by traditional methods. Moreover, the O-arylated products so formed can be directly transformed into substituted benzofurans in a single operation." @default.
• W2071293492 created "2016-06-24" @default.
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• W2071293492 date "2010-07-06" @default.
• W2071293492 modified "2023-10-17" @default.
• W2071293492 title "Pd-Catalyzed O-Arylation of Ethyl Acetohydroximate: Synthesis of <i>O</i>-Arylhydroxylamines and Substituted Benzofurans" @default.
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• W2071293492 doi "https://doi.org/10.1021/ja1044874" @default.
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