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- W2071350668 abstract "Abstract Photolysis of 1,6-cyclodecanedione, both in the crystalline state and in solution, fails to lead to any Norrish/Yang type II products despite the fact that the conformation of the molecule in the solid state is nearly ideal for hydrogen atom abstraction. Based on X-ray crystal structure and molecular modeling studies, it is argued that γ-hydrogen abstraction does occur in the solid state, but that closure of the resulting 1,4-biradical is slower than reverse hydrogen atom transfer owing to difficulty in forming the expected 8-membered ring-containing photoproduct. In solution, on the other hand, molecular mechanics calculations indicate that the lack of photoreactivity of 1,6-cyclodecanedione stems from the fact that this molecule exists nearly exclusively in a conformation for which γ-hydrogen abstraction is sterically impossible." @default.
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- W2071350668 date "1996-02-01" @default.
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- W2071350668 title "On the Conformational Analysis and Photochemical Reactivity of 1,6-Cyclodecanedione" @default.
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- W2071350668 doi "https://doi.org/10.1080/10587259608046034" @default.
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