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- W2071372262 abstract "The title compound, [K(C12H24O6)(C4H8O)2]I, has iodide anions on crystallographic twofold rotation axes and cations in general positions. The coordination of potassium is distorted hexagonal bipyramidal, with an 18-crown-6 ligand as an equatorial belt and two axial tetrahydrofuran ligands. Distortion is marked, consisting mainly of a significant bending of the axial arrangement [O—K—O = 148.53 (13)°] and a shortening of the two equatorial K—O bonds closest to the axial O atoms. This conformation is unprecedented in the previous reports of this cation, with almost thirty different occurrences in nearly twenty crystal structures." @default.
- W2071372262 created "2016-06-24" @default.
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- W2071372262 date "2003-11-29" @default.
- W2071372262 modified "2023-10-16" @default.
- W2071372262 title "(18-Crown-6)-bis(tetrahydrofuran)potassium iodide" @default.
- W2071372262 cites W2128179591 @default.
- W2071372262 doi "https://doi.org/10.1107/s160053680302676x" @default.
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