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- W2071375627 abstract "Abstract gem -Dialkylation or alkylative reduction of α-unbranched aliphatic aldehydes 1 is advantageously achieved by reaction of the corresponding gem -bistriflates 2 with di- n -alkylcyanocuprates or di- sec - and di- tert -alkylcyanocuprates respectively. The reaction of α-branched gem -bistriflates 2 with dialkylcyanocuprates in the presence of boron trifluoride affords the olefins 6 in good yield." @default.
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- W2071375627 date "1994-01-01" @default.
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- W2071375627 title "Geminal dialkylation, alkylative reduction and olefination of aliphatic aldehydes. Reaction of gem-bistriflates with higher order dialkylcyanocuprates." @default.
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- W2071375627 doi "https://doi.org/10.1016/s0040-4020(01)89331-5" @default.
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