FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2071396037> ?p ?o ?g. }

• W2071396037 endingPage "598" @default.
• W2071396037 startingPage "565" @default.
• W2071396037 abstract "This paper describes a study concerning the interaction of molecular oxygen (O2) and nitrous oxide (N2O) with the clean Si(100) 2 × 1 surface in ultrahigh vacuum at 300 K. Differential reflectometry (DR) in the photon energy range of 1.5–4.5 eV, Auger electron spectroscopy (AES) and low energy electron diffraction (LEED) have been used to monitor these solid-gas reactions. With this combination of techniques it is possible to make an analysis of the (geometric and electronic) structure and chemical composition of the surface layer. The aim of the present study was to give a description of the geometric nature of the oxygen covered Si(100) surface. For that purpose we have used both molecular (O2) and atomic oxygen (as released by decomposition of N2O) to oxidize the clean Si(100)2 × 1 surface. In view of the experimental results we propose a model in which the decomposition of N2O into a chemisorbed oxygen atom and a desorbing N2 molecule is described by a coupled reaction mechanism. The initial reaction probability was found to be (2.4 ± 0.2) × 10 −5. The principal result is that the decomposition of N2O only occurs at those Si atoms which have a dimer and dangling bond, i.e., mainly first layer Si atoms. The concentration of defects in our clean Si(100)2 × 1 surface was estimated to be a few percent. Every stage of the reaction involves the formation of bridging oxygen, saturation occurring at monolayer coverage. Thus the interface between the monatomic oxygen adlayer and the underlying Si lattice is essentially abrupt. The interaction of O2 with the clean Si(100)2 × 1 surface is found to lead to chemisorption, with the initial sticking probability: s(0) = 0.09 ± 0.01. At coverages below 0.5 monolayer the adsorption of O2 can be described by a dissociative process on the first layer Si atoms. The empty dangling bond orbital which is related to the lowered Si atom of the asymmetric dimer does not show appreciable reactivity towards the O2 molecule. In the intermediate coverage range (0.5 – 1 monolayer oxygen) incorporation of oxygen into the subsurface Si lattice and adsorption of a molecular oxygen species occur simultaneously. Due to this species, ∽ 20% of the (dimer and dangling bond) surface states are left unsaturated. Beyond monolayer coverage penetration of oxygen into the Si lattice is the limiting process. Careful measurements of the SiL23VV Auger spectra have led to more definite conclusions about the binding state of oxygen: the SiO 83 eV Auger peak can be exclusively related to Si-O bond formation on the first layer Si atoms." @default.
• W2071396037 created "2016-06-24" @default.
• W2071396037 creator A5008001536 @default.
• W2071396037 creator A5083264720 @default.
• W2071396037 creator A5086555741 @default.
• W2071396037 date "1987-02-01" @default.
• W2071396037 modified "2023-09-26" @default.
• W2071396037 title "Adsorption of atomic oxygen (N2O) on a clean Si(100) surface and its influence on the surface state density; A comparison with O2" @default.
• W2071396037 cites W1548177543 @default.
• W2071396037 cites W1967083888 @default.
• W2071396037 cites W1968744333 @default.
• W2071396037 cites W1969069154 @default.
• W2071396037 cites W1971339061 @default.
• W2071396037 cites W1974664861 @default.
• W2071396037 cites W1975488197 @default.
• W2071396037 cites W1979654866 @default.
• W2071396037 cites W1987495202 @default.
• W2071396037 cites W1987579287 @default.
• W2071396037 cites W1989286146 @default.
• W2071396037 cites W1990715293 @default.
• W2071396037 cites W1993630871 @default.
• W2071396037 cites W1996757887 @default.
• W2071396037 cites W1998484861 @default.
• W2071396037 cites W1999091225 @default.
• W2071396037 cites W2000726168 @default.
• W2071396037 cites W2008597722 @default.
• W2071396037 cites W2008782440 @default.
• W2071396037 cites W2017374384 @default.
• W2071396037 cites W2020983705 @default.
• W2071396037 cites W2022599032 @default.
• W2071396037 cites W2028479111 @default.
• W2071396037 cites W2033261083 @default.
• W2071396037 cites W2039568857 @default.
• W2071396037 cites W2046096144 @default.
• W2071396037 cites W2047337389 @default.
• W2071396037 cites W2051181345 @default.
• W2071396037 cites W2051443775 @default.
• W2071396037 cites W2051764843 @default.
• W2071396037 cites W2057481332 @default.
• W2071396037 cites W2058564509 @default.
• W2071396037 cites W2062677926 @default.
• W2071396037 cites W2064741608 @default.
• W2071396037 cites W2070462232 @default.
• W2071396037 cites W2070746207 @default.
• W2071396037 cites W2074034911 @default.
• W2071396037 cites W2076125746 @default.
• W2071396037 cites W2076468654 @default.
• W2071396037 cites W2082598926 @default.
• W2071396037 cites W2083601382 @default.
• W2071396037 cites W2084473096 @default.
• W2071396037 cites W2086142577 @default.
• W2071396037 cites W2088343999 @default.
• W2071396037 cites W2089463010 @default.
• W2071396037 cites W2092846619 @default.
• W2071396037 cites W2094267082 @default.
• W2071396037 cites W2096516455 @default.
• W2071396037 cites W2106603672 @default.
• W2071396037 cites W2115434338 @default.
• W2071396037 cites W2117495759 @default.
• W2071396037 cites W2131226436 @default.
• W2071396037 cites W2167322046 @default.
• W2071396037 cites W2168431130 @default.
• W2071396037 cites W4235687059 @default.
• W2071396037 cites W4237025409 @default.
• W2071396037 cites W4248675028 @default.
• W2071396037 doi "https://doi.org/10.1016/0039-6028(87)90226-3" @default.
• W2071396037 hasPublicationYear "1987" @default.
• W2071396037 type Work @default.
• W2071396037 sameAs 2071396037 @default.
• W2071396037 citedByCount "97" @default.
• W2071396037 countsByYear W20713960372012 @default.
• W2071396037 countsByYear W20713960372014 @default.
• W2071396037 countsByYear W20713960372018 @default.
• W2071396037 crossrefType "journal-article" @default.
• W2071396037 hasAuthorship W2071396037A5008001536 @default.
• W2071396037 hasAuthorship W2071396037A5083264720 @default.
• W2071396037 hasAuthorship W2071396037A5086555741 @default.
• W2071396037 hasConcept C113196181 @default.
• W2071396037 hasConcept C120665830 @default.
• W2071396037 hasConcept C121332964 @default.
• W2071396037 hasConcept C147789679 @default.
• W2071396037 hasConcept C150394285 @default.
• W2071396037 hasConcept C151505824 @default.
• W2071396037 hasConcept C178790620 @default.
• W2071396037 hasConcept C185544564 @default.
• W2071396037 hasConcept C185592680 @default.
• W2071396037 hasConcept C207114421 @default.
• W2071396037 hasConcept C20885615 @default.
• W2071396037 hasConcept C2524010 @default.
• W2071396037 hasConcept C25442681 @default.
• W2071396037 hasConcept C2776799497 @default.
• W2071396037 hasConcept C32424582 @default.
• W2071396037 hasConcept C33790079 @default.
• W2071396037 hasConcept C33923547 @default.
• W2071396037 hasConcept C43617362 @default.
• W2071396037 hasConcept C540031477 @default.
• W2071396037 hasConcept C544956773 @default.
• W2071396037 hasConcept C55493867 @default.

• next