FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2071402144> ?p ?o ?g. }

• W2071402144 endingPage "4380" @default.
• W2071402144 startingPage "4373" @default.
• W2071402144 abstract "Scanning transmission X-ray microscopy combined with near-edge X-ray absorption fine structure spectroscopy (STXM/NEXAFS) and optical microscopy coupled with Fourier transform infrared spectroscopy (micro-FTIR) have been applied to observe hygroscopic growth and chemical changes in malonic acid particles deposited on substrates. The extent of the hygroscopic growth of particles has been quantified in terms of the corresponding water-to-solute ratios (WSR) based on STXM/NEXAFS and micro-FTIR data sets. WSR values derived separately from two applied methods displayed a remarkable agreement with previous data reported in the literature. Comparison of NEXAFS and FTIR spectra acquired at different relative humidity (RH) shows efficient keto−enol tautomerization of malonic acid, with the enol form dominating at higher RH. The keto−enol equilibrium constants were calculated using relevant peak intensities in the carbon and oxygen K-edge NEXAFS spectra as a function of RH. We report strong dependence of the equilibrium constant on RH, with measured values of 0.18 ± 0.03, 1.11 ± 0.14, and 2.33 ± 0.37 corresponding to 2, 50, and 90% RH, respectively. Enols are important intermediates in aldol condensation reactions pertaining to formation and atmospheric aging of secondary organic aerosol (SOA). The present knowledge assumes that constituents of atmospheric deliquesced particles undergo aqueous chemistry with kinetic and equilibrium constants analogous to reactions in bulk solutions, which would estimate absolute dominance of the keto form of carboxylic acids. For instance, the keto−enol equilibrium constant of malonic acid in diluted aqueous solution is <10−4. Our results suggest that in deliquesced micrometer-size particles, carboxylic acids may exist in predominantly enol forms that need to be explicitly considered in atmospheric aerosol chemistry." @default.
• W2071402144 created "2016-06-24" @default.
• W2071402144 creator A5018387935 @default.
• W2071402144 creator A5032668969 @default.
• W2071402144 creator A5087043452 @default.
• W2071402144 date "2011-04-11" @default.
• W2071402144 modified "2023-10-16" @default.
• W2071402144 title "Spectroscopic Evidence of Keto−Enol Tautomerism in Deliquesced Malonic Acid Particles" @default.
• W2071402144 cites W1971484520 @default.
• W2071402144 cites W1980725928 @default.
• W2071402144 cites W1984522603 @default.
• W2071402144 cites W1987399344 @default.
• W2071402144 cites W1987856304 @default.
• W2071402144 cites W1990726653 @default.
• W2071402144 cites W1991934907 @default.
• W2071402144 cites W1993587484 @default.
• W2071402144 cites W1994274631 @default.
• W2071402144 cites W2000931437 @default.
• W2071402144 cites W2003648458 @default.
• W2071402144 cites W2008994119 @default.
• W2071402144 cites W2018499373 @default.
• W2071402144 cites W2031102891 @default.
• W2071402144 cites W2034568090 @default.
• W2071402144 cites W2042528592 @default.
• W2071402144 cites W2049044815 @default.
• W2071402144 cites W2053261594 @default.
• W2071402144 cites W2057605129 @default.
• W2071402144 cites W2063987765 @default.
• W2071402144 cites W2066278291 @default.
• W2071402144 cites W2067768216 @default.
• W2071402144 cites W2069724605 @default.
• W2071402144 cites W2073265149 @default.
• W2071402144 cites W2077067861 @default.
• W2071402144 cites W2080493512 @default.
• W2071402144 cites W2081668232 @default.
• W2071402144 cites W2084387349 @default.
• W2071402144 cites W2086273435 @default.
• W2071402144 cites W2088031271 @default.
• W2071402144 cites W2089943444 @default.
• W2071402144 cites W2090578881 @default.
• W2071402144 cites W2091518851 @default.
• W2071402144 cites W2103639584 @default.
• W2071402144 cites W2106029740 @default.
• W2071402144 cites W2109695616 @default.
• W2071402144 cites W2113329804 @default.
• W2071402144 cites W2116507044 @default.
• W2071402144 cites W2117703115 @default.
• W2071402144 cites W2117990130 @default.
• W2071402144 cites W2126507747 @default.
• W2071402144 cites W2139913170 @default.
• W2071402144 cites W2144366286 @default.
• W2071402144 cites W2155433774 @default.
• W2071402144 cites W2155516010 @default.
• W2071402144 cites W2164168217 @default.
• W2071402144 cites W2313449776 @default.
• W2071402144 cites W2320464910 @default.
• W2071402144 cites W4236270162 @default.
• W2071402144 cites W7925918 @default.
• W2071402144 doi "https://doi.org/10.1021/jp112360x" @default.
• W2071402144 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/21480651" @default.
• W2071402144 hasPublicationYear "2011" @default.
• W2071402144 type Work @default.
• W2071402144 sameAs 2071402144 @default.
• W2071402144 citedByCount "53" @default.
• W2071402144 countsByYear W20714021442012 @default.
• W2071402144 countsByYear W20714021442013 @default.
• W2071402144 countsByYear W20714021442014 @default.
• W2071402144 countsByYear W20714021442015 @default.
• W2071402144 countsByYear W20714021442016 @default.
• W2071402144 countsByYear W20714021442017 @default.
• W2071402144 countsByYear W20714021442018 @default.
• W2071402144 countsByYear W20714021442019 @default.
• W2071402144 countsByYear W20714021442020 @default.
• W2071402144 countsByYear W20714021442021 @default.
• W2071402144 countsByYear W20714021442022 @default.
• W2071402144 countsByYear W20714021442023 @default.
• W2071402144 crossrefType "journal-article" @default.
• W2071402144 hasAuthorship W2071402144A5018387935 @default.
• W2071402144 hasAuthorship W2071402144A5032668969 @default.
• W2071402144 hasAuthorship W2071402144A5087043452 @default.
• W2071402144 hasConcept C10710636 @default.
• W2071402144 hasConcept C110715899 @default.
• W2071402144 hasConcept C111233374 @default.
• W2071402144 hasConcept C113196181 @default.
• W2071402144 hasConcept C119824511 @default.
• W2071402144 hasConcept C121332964 @default.
• W2071402144 hasConcept C127413603 @default.
• W2071402144 hasConcept C147535893 @default.
• W2071402144 hasConcept C147789679 @default.
• W2071402144 hasConcept C160892712 @default.
• W2071402144 hasConcept C161790260 @default.
• W2071402144 hasConcept C178790620 @default.
• W2071402144 hasConcept C184651966 @default.
• W2071402144 hasConcept C185592680 @default.
• W2071402144 hasConcept C2776596982 @default.
• W2071402144 hasConcept C2777495281 @default.
• W2071402144 hasConcept C32891209 @default.
• W2071402144 hasConcept C42360764 @default.

• next