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- W2071413706 abstract "Mulliken-type charge-transfer complexes have been formed between basic half-sandwich compounds and SO2 when [M(η5-C5R5)(CO)2](M = Rh or Ir; R5= Me5, H5 or H4CF3), [Ir(η5-C5H5)(CO)(C2H4)], and [M(η5-C5H5)(C2H4)2](M = Co, Rh or Ir) are isolated in SO2-doped argon matrices at 20 K; the ν(CO) bands of the complexes are shifted to high frequency of those of the precursor molecules and prominent charge-transfer bands are observed; the same species have been detected when the compounds [M (η5-C5Me5)(CO)2](M = Rh or Ir) are embedded in polyethylene discs and treated with SO2 at 213–298 K; the enthalpy of complexation of [Ir(η5-C5Me5)(CO)2] with SO2 is –13 ± 3 kJ mol–1." @default.
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- W2071413706 date "1994-01-01" @default.
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- W2071413706 title "Charge-transfer interactions between sulfur dioxide and group 8 half-sandwich complexes" @default.
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- W2071413706 doi "https://doi.org/10.1039/dt9940003515" @default.
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