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- W2071440031 abstract "Abstract The attempts to produce higher and higher charge states of anionic metal clusters in Penning traps by attachment of simultaneously stored electrons run into a dilemma: On the one hand, the size of the clusters, which are initially only singly charged, has to be increased to accommodate additional electrons. On the other hand, in order to attach to already highly-charged particles, electrons have to overcome the respective Coulomb barriers. Thus, for the conventional electron-bath technique the electrons need to be created at correspondingly higher trapping potentials. This leads to a conflict as the “critical mass”, above which the ion orbits are no longer stable, is inversely proportional to the trapping potential. However, as the critical mass is actually an upper limit of the mass-over-charge ratio, the introduction of a stepwise charging-up by repeated electron bathing after increase of the trapping potential allows one to reach higher and higher charge states." @default.
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- W2071440031 date "2012-03-01" @default.
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- W2071440031 title "Lifting of the trapping potential during ion storage for multi-anion production in a Penning trap" @default.
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- W2071440031 doi "https://doi.org/10.1016/j.ijms.2011.12.009" @default.
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