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• W2071453437 abstract "Electrochemical sensors for copper ions in environmental samples were prepared by modifying gold electrodes with l-cysteine by self-assembly. The adsorption of l-cysteine on gold electrodes was studied by electrochemical reductive desorption in 0.5 M KOH, and the interaction of l-cysteine with copper ions was investigated by cyclic voltammetry, chronoamperometry and X-ray photoelectron spectroscopy. At low concentrations the ratio of l-cysteine to bound Cu(II) is 2:1. At higher concentrations (0.1 M) copper reacts with adsorbed cysteine forming copper sulfide on the electrode surface. On a modified l-cysteine gold electrode, Osteryoung square wave voltammetric determination of Cu(II) with a detection limit below 5 ppb has been demonstrated." @default.
• W2071453437 created "2016-06-24" @default.
• W2071453437 creator A5045621149 @default.
• W2071453437 creator A5049859531 @default.
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• W2071453437 date "2001-12-01" @default.
• W2071453437 modified "2023-10-05" @default.
• W2071453437 title "Characterisation of gold electrodes modified with self-assembled monolayers of l-cysteine for the adsorptive stripping analysis of copper" @default.
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• W2071453437 doi "https://doi.org/10.1016/s0022-0728(01)00649-0" @default.
• W2071453437 hasPublicationYear "2001" @default.
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