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• W2071479982 abstract "The complexes [Pt2L2(μ-dppm)](ClO4)2 (1) and {[Pt2L2(μ-dppm)Li(CH3CN)2](ClO4)3}n (2), where HL is 6-[4-(diethoxyphosphorylmethyl)phenyl]-2,2′-bipyridinyl and dppm is bis(diphenylphosphino)methane, have been synthesized and characterized. In complex 1 the platinum(II) center adopts a distorted square planar coordination geometry. The polymer 2 exhibits a stairstep configuration with one-dimensional Pt(II)NˆNˆCPO- Li(I)-OPCˆNˆNPt(II) mixed-metal units which are linked through dppm. Both complexes have metal-metal interaction with Pt–Pt distances of 3.325(2) and 3.1432(9) Å, respectively, and display strong metal-metal-to-ligand charge-transfer (MMLCT) triplet state emission. The density-functional-theory calculation was used to interpret the absorption spectra of the complexes." @default.
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• W2071479982 date "2007-12-01" @default.
• W2071479982 modified "2023-10-18" @default.
• W2071479982 title "Unprecedented 1D Mixed-metal Polynuclear Cyclometalated Platinum Complexes: Synthesis, Structural Characterization and Spectroscopic Properties" @default.
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• W2071479982 doi "https://doi.org/10.1002/cjoc.200790336" @default.
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