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• W2071483736 endingPage "1016" @default.
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• W2071483736 abstract "Reaction of copper(I) chloride with 1,3-imidazoline-2-thione (imzSH) in the presence of Ph3P in 1:2:2 or 1:1:2 (M:L:PPh3) molar ratios yielded a compound of unusual composition, [Cu2(imzSH)(PPh3)4Cl2] · CH3OH (1), whose X-ray crystallography has shown that its crystals consist of four coordinated [CuCl(1κS-imzSH)(PPh3)2] (1a), and three coordinated [Cu(PPh3)2Cl] (1b) independent molecules in the same unit cell. In contrast, crystals of complexes of copper(I) bromide/iodide are formed by single molecules of [CuBr(1κS-imzSH)(PPh3)2] · H2O (2) and [CuI(1κS-imzSH)(PPh3)2] (3), respectively, similar to molecule 1a. The related ligand, 1,3-benzimidazoline-2-thione (bzimSH) formed a complex [CuBr(1κS-bzimSH)(PPh3)2] · CH3COCH3 (4), similar to 2. The formation of 1a and 1b has been also revealed by NMR spectroscopy. The NMR spectra of 2–4 also showed weak signals indicating formation of compounds similar to 1b. It reveals that the lability of the Cu–S bond varies in the order: Cl ≫ Br ∼ I. Weak interactions {e.g. C–H⋯π electrons of ring, –NH⋯halogens/oxygen, C–H⋯halogens/oxygen, π⋯π (between rings)} have played an important role in building 2D chains of complexes 1–4." @default.
• W2071483736 created "2016-06-24" @default.
• W2071483736 creator A5067180267 @default.
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• W2071483736 date "2008-02-01" @default.
• W2071483736 modified "2023-10-18" @default.
• W2071483736 title "Heterocyclic thioamides of copper(I): Synthesis and crystal structures of copper complexes with 1,3-imidazoline-2-thiones in the presence of triphenyl phosphine" @default.
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• W2071483736 doi "https://doi.org/10.1016/j.poly.2007.11.036" @default.
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