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• W2071490265 abstract "In this article, we present conductivities (Λ), densities () and viscosities (η) of Hept4NI in o-toluidine, o-xylene and 2-nitrotoluene at 298.15 K. Limiting molar conductivity (Λ0), association constant (KA) and distance of the closest approach of the ions (R) for Hept4NI in 2-nitrotoluene have been evaluated using the Fuoss conductance equation. The Walden product and Gibb’s energy change are obtained and discussed. Deviation of the conductometric curves (Λ vs. √c) from linearity for Hept4NI in o-toluidine and o-xylene indicates triple-ion formation, therefore the corresponding conductance data have been analysed by the Fuoss–Kraus theory of triple ions. Observed molar conductivities have been explained by the ion-pair (M+ + X− ↔ MX) and triple-ion (2 M+ + X− ↔ M2X+, M+ + 2X− ↔ MX2−) formation. Limiting apparent molar volumes (), experimental slopes () derived from the Masson equation and viscosity A and B-coefficients using the Jones–Dole equation have been interpreted in terms of ion–ion and ion–solve..." @default.
• W2071490265 created "2016-06-24" @default.
• W2071490265 creator A5052175601 @default.
• W2071490265 creator A5086684645 @default.
• W2071490265 date "2014-10-08" @default.
• W2071490265 modified "2023-09-23" @default.
• W2071490265 title "Essential foundation of triple-ion and ion-pair formation of tetraheptylammonium iodide (Hept4NI) salt in organic solvents investigated by physicochemical approach" @default.
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• W2071490265 doi "https://doi.org/10.1080/00319104.2013.864565" @default.
• W2071490265 hasPublicationYear "2014" @default.
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