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W2071490344 endingPage "210" @default.
W2071490344 startingPage "199" @default.
W2071490344 abstract "Abstract The reactions of [NBu4]2[cis-Pt(C6F5)2(CCR2] (R=1Bu or SiMe3) wiht CoCl2·6H2O in a ]: 1 molar ratio yielded the paramagnetic binuclear species [NBu 4 ] 2 cis-Pt) C 6 F 5 ) 2 (μ-CCR) 2 CoCl 2 ] (R = 1 Bu (ia) . SiMe1 (1b)) in which the cobalt(II) chloride is coordinated η2-side on to both alkynyl ligands of the platinum fragment. Similar treatment of [NBu4]2[Pt(CCR)2]·2H2O (R = 1Bu or SiMe3) with CoCl2·6H2O in a 1:2 molar ratio gave the corresponding trinuclear 1:2 adducts [NBu4]2[Pt(μ-CCR)4 CoCl22] (2). The compounds were characterised by analytical and spectroscopic data and, in addition, the crystal structures of a representative complex of each category were determined: 1b·acetone and 2a·acetone. Surprisingly, whilst in the binuclear anion [Pt(C6F5)2(CCSiMe3)2CoCl2]2− the cobalt atom is well embedded by the alkynyl fragments giving a precisely planar PtC4Co core and a very long Pt…Co separation (3.446(3) A). in the trinuclear derivative [Pt(CC1Bi)4CoCl22]2− the PtC4Co cores are highed imposing significantly shorter Pt…Co distances (3.077(3) A)." @default.
W2071490344 created "2016-06-24" @default.
W2071490344 creator A5004647039 @default.
W2071490344 creator A5032946809 @default.
W2071490344 creator A5041817693 @default.
W2071490344 creator A5061450850 @default.
W2071490344 date "1997-11-01" @default.
W2071490344 modified "2023-09-25" @default.
W2071490344 title "Synthesis, characterisation and NMR study of paramagnetic heteropolynuclear anionic PtCo species. Crystal structures of [NBu4]2[cis-Pt(C6F5)2(CCSiMe3)2CoCl3)2·0.5(CH3)2CO and NBu4]2[Pt(CCtBu)42]·1.5(CH3)2CO" @default.
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