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• W2071491865 abstract "Static and dynamic laser light scattering were used to bring evidence of large-scale supramolecular structure in solutions of low molar mass electrolytes, nonelectrolytes, and mixtures of liquids. It was shown that solutes are distributed inhomogeneously on large length scales. Regions of higher and lower solute concentration exist in solution and give sufficient scattering contrast for experimental observation. A detailed light scattering study showed that these regions can be characterized as close-to-spherical discrete domains of higher solute density in a less dense rest of solution. These domains do contain solvent inside and can be therefore characterized as loose associates (giant clusters, aggregates). Their size distributions are significantly broad, ranging up to several hundreds of nanometers. Characteristic sizes of these inhomogenities thus exceed angstrom dimensions of individual molecules by several orders of magnitude. The number of solute molecules per domain varies approximately in the range 103 − 108. Phenomena described were observed in a very broad range of solutes and solvents. Among others, selected data on most common substances of great chemical and biological importance such as sodium chloride, citric acid, glucose, urea, acetic acid, and ethanol are presented." @default.
• W2071491865 created "2016-06-24" @default.
• W2071491865 creator A5047489056 @default.
• W2071491865 date "2006-02-03" @default.
• W2071491865 modified "2023-10-12" @default.
• W2071491865 title "Large-Scale Supramolecular Structure in Solutions of Low Molar Mass Compounds and Mixtures of Liquids: I. Light Scattering Characterization" @default.
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• W2071491865 doi "https://doi.org/10.1021/jp0569335" @default.
• W2071491865 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/16509731" @default.
• W2071491865 hasPublicationYear "2006" @default.
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