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- W2071501487 abstract "Abstract Palladium and tungsten complexes containing the bifunctional ligand 4‐diphenylphosphanylcatechol (L 1 ) have been synthesized. The catecholate functionality strongly binds to titanium dioxide nanoparticles, effectively anchoring the complexes to the TiO 2 surface. Solid‐state 31 P NMR spectroscopy was used to probe the surface‐bound compounds. Diffuse reflectance infrared spectroscopy also provided data on surface‐bound tungsten carbonyl complexes. Preliminary experiments show that the palladium phosphane complex [PdBr 2 (L 1 ) 2 ] supported on TiO 2 catalyzes the Sonogashira coupling of phenylacetylene with 4‐iodonitrobenzene. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)" @default.
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- W2071501487 date "2005-01-27" @default.
- W2071501487 modified "2023-10-12" @default.
- W2071501487 title "Titanium Dioxide Nanoparticles Functionalized with Pd and W Complexes of a Catecholphosphane Ligand" @default.
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- W2071501487 doi "https://doi.org/10.1002/ejic.200400584" @default.
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