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- W2071521796 abstract "Single crystals of the suboxometallates A9MO4 (A = Rb, Cs;M = Al, Ga, Fe, Sc) were prepared by reaction of stoichiometric mixtures of M2O3 with alkali metals and their oxides A2O. They crystallize in the tetragonal Cs9InO4 structure type (space group I4/mcm) and contain ortho-oxometallate(III) anions in a metallic matrix. Cesium can be partially substituted by rubidium, as shown for phases of arbitrary compositions (RbxCs1–x)Cs8GaO4 (x = 0.57) and (RbxCs1–x)Cs8InO4 (x = 0.87). The substitution leads to statistical occupation of one crystallographic position. The same holds for substitutions of M, as in Cs9(AlxIn1–x)O4 (x = 0.51) and Cs9(ScxIn1–x)O4 (x = 0.68)." @default.
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- W2071521796 date "2009-10-01" @default.
- W2071521796 modified "2023-10-14" @default.
- W2071521796 title "Die Suboxometallate A9MO4(A = Rb, Cs; M = Al, Ga, In, Fe, Sc)" @default.
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- W2071521796 doi "https://doi.org/10.1002/zaac.200900193" @default.
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