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- W2071541578 abstract "Gold-catalyzed intermolecular oxidation of carboxylates of primary or secondary propargylic alcohols are realized with excellent regioselectivity, which is ascribed to inductive polarization of the C-C triple bond by the electron-withdrawing carboxy group. The gold carbene intermediates thus generated undergo selective 1,2-acyloxy migration over a 1,2-C-H insertion, and the selectivities could be dramatically improved by the use of a P,S-bidentate ligand, which is proposed to enable the formation of tris-coordinated and hence less electrophilic gold carbene species. α-Carboxy α,β-unsaturated ketones/aldehydes can be obtained with fair to excellent yields." @default.
- W2071541578 created "2016-06-24" @default.
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- W2071541578 date "2013-09-24" @default.
- W2071541578 modified "2023-09-30" @default.
- W2071541578 title "Gold-catalyzed regioselective oxidation of propargylic carboxylates: a reliable access to α-carboxy-α,β-unsaturated ketones/aldehydes" @default.
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- W2071541578 doi "https://doi.org/10.3762/bjoc.9.227" @default.
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