FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2071550503> ?p ?o ?g. }

• W2071550503 endingPage "137" @default.
• W2071550503 startingPage "125" @default.
• W2071550503 abstract "Infrared chemiluminescence from HCl has been observed in “arrested relaxation” experiments to yield vibrational and rotational distributions from the reactions H+Cl2, SCl2 and PCl3, where H denotes hydrogen atoms with translational energy of 0.45 eV. The following relative populations were determined: Nv-1: Nv-2: Nv-3: Nv-4: Nv-5: Nv-6 = 0.89:1.00:0.84:0.47:0.26:0.11 for H+Cl2: Nv-1: Nv-2: Nv-3: Nv-4: Nv-5: Nv-6 = 0.80:1.00:0.72:0.48:0.24:0.10 for H+SCl2: Nv-1: Nv-2: Nv-3: Nv-4: Nv-5 = 0.79:1.00:0.88:0.36:0.14 for H+PCl3. In all three reaction systems the chemiluminescence was attributed to the primary chlorine abstraction. Comparison with the results of the thermal processes (0.04 eV hydrogen atoms) led to the following conclusions: for H+Cl2 the excess of translational energy is transformed into translational product energy and rotational energy of the molecule HCl; for H+SCl2 the excess of translational energy is transformed mainly into translational energy of the products and perhaps internal energy of SCl; for H+PCl3 the excess of translational energy allows the observation of the primary abstraction reaction, which could in earlier experiments at 300 K not be separated from secondary chemiluminescent processes. Bimodal rotational distributions were confirmed for several vibrational states of HCl formed in the systems H+Cl2, and H+SCl2. Bimodal rotational distributions were also detected in the chemiluminescent reaction H(0.04 eV)+CH3SCl → HCl(v ⩽ 5)+CH3S." @default.
• W2071550503 created "2016-06-24" @default.
• W2071550503 creator A5006318551 @default.
• W2071550503 creator A5028671803 @default.
• W2071550503 creator A5047053024 @default.
• W2071550503 date "1984-02-01" @default.
• W2071550503 modified "2023-10-14" @default.
• W2071550503 title "Infrared chemiluminescence in the reactions of 0.45 eV hydrogen atoms with Cl2, SCl2 and PCl3" @default.
• W2071550503 cites W1491733668 @default.
• W2071550503 cites W1617399777 @default.
• W2071550503 cites W1963691421 @default.
• W2071550503 cites W1969371647 @default.
• W2071550503 cites W1973606040 @default.
• W2071550503 cites W1975141787 @default.
• W2071550503 cites W1976493577 @default.
• W2071550503 cites W1978631493 @default.
• W2071550503 cites W1978988532 @default.
• W2071550503 cites W1980647539 @default.
• W2071550503 cites W1987590679 @default.
• W2071550503 cites W1988860647 @default.
• W2071550503 cites W2000981667 @default.
• W2071550503 cites W2002149530 @default.
• W2071550503 cites W2027921249 @default.
• W2071550503 cites W2046295856 @default.
• W2071550503 cites W2046857621 @default.
• W2071550503 cites W2049627183 @default.
• W2071550503 cites W2052259793 @default.
• W2071550503 cites W2054537052 @default.
• W2071550503 cites W2076710426 @default.
• W2071550503 cites W2077579871 @default.
• W2071550503 cites W2078182413 @default.
• W2071550503 cites W2084409776 @default.
• W2071550503 cites W2085102122 @default.
• W2071550503 cites W2086253267 @default.
• W2071550503 cites W2087344755 @default.
• W2071550503 cites W2091713533 @default.
• W2071550503 cites W2096725629 @default.
• W2071550503 cites W2142043828 @default.
• W2071550503 cites W2317929389 @default.
• W2071550503 cites W2624060975 @default.
• W2071550503 cites W273611335 @default.
• W2071550503 doi "https://doi.org/10.1016/0301-0104(84)80010-5" @default.
• W2071550503 hasPublicationYear "1984" @default.
• W2071550503 type Work @default.
• W2071550503 sameAs 2071550503 @default.
• W2071550503 citedByCount "14" @default.
• W2071550503 countsByYear W20715505032013 @default.
• W2071550503 countsByYear W20715505032021 @default.
• W2071550503 crossrefType "journal-article" @default.
• W2071550503 hasAuthorship W2071550503A5006318551 @default.
• W2071550503 hasAuthorship W2071550503A5028671803 @default.
• W2071550503 hasAuthorship W2071550503A5047053024 @default.
• W2071550503 hasConcept C113196181 @default.
• W2071550503 hasConcept C120665830 @default.
• W2071550503 hasConcept C121332964 @default.
• W2071550503 hasConcept C134121241 @default.
• W2071550503 hasConcept C145802702 @default.
• W2071550503 hasConcept C147789679 @default.
• W2071550503 hasConcept C158355884 @default.
• W2071550503 hasConcept C178790620 @default.
• W2071550503 hasConcept C184779094 @default.
• W2071550503 hasConcept C185592680 @default.
• W2071550503 hasConcept C2992827107 @default.
• W2071550503 hasConcept C32909587 @default.
• W2071550503 hasConcept C512968161 @default.
• W2071550503 hasConcept C75473681 @default.
• W2071550503 hasConcept C84662259 @default.
• W2071550503 hasConcept C97355855 @default.
• W2071550503 hasConceptScore W2071550503C113196181 @default.
• W2071550503 hasConceptScore W2071550503C120665830 @default.
• W2071550503 hasConceptScore W2071550503C121332964 @default.
• W2071550503 hasConceptScore W2071550503C134121241 @default.
• W2071550503 hasConceptScore W2071550503C145802702 @default.
• W2071550503 hasConceptScore W2071550503C147789679 @default.
• W2071550503 hasConceptScore W2071550503C158355884 @default.
• W2071550503 hasConceptScore W2071550503C178790620 @default.
• W2071550503 hasConceptScore W2071550503C184779094 @default.
• W2071550503 hasConceptScore W2071550503C185592680 @default.
• W2071550503 hasConceptScore W2071550503C2992827107 @default.
• W2071550503 hasConceptScore W2071550503C32909587 @default.
• W2071550503 hasConceptScore W2071550503C512968161 @default.
• W2071550503 hasConceptScore W2071550503C75473681 @default.
• W2071550503 hasConceptScore W2071550503C84662259 @default.
• W2071550503 hasConceptScore W2071550503C97355855 @default.
• W2071550503 hasIssue "1" @default.
• W2071550503 hasLocation W20715505031 @default.
• W2071550503 hasOpenAccess W2071550503 @default.
• W2071550503 hasPrimaryLocation W20715505031 @default.
• W2071550503 hasRelatedWork W1993052090 @default.
• W2071550503 hasRelatedWork W2028546563 @default.
• W2071550503 hasRelatedWork W2034582226 @default.
• W2071550503 hasRelatedWork W2065285972 @default.
• W2071550503 hasRelatedWork W2071550503 @default.
• W2071550503 hasRelatedWork W2080998374 @default.
• W2071550503 hasRelatedWork W2401463829 @default.
• W2071550503 hasRelatedWork W2475465508 @default.
• W2071550503 hasRelatedWork W2949184651 @default.
• W2071550503 hasRelatedWork W2952649848 @default.

• next