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• W2071566291 abstract "Structural changes and cation dynamics of a fast ion conducting glass 0.75AgI–0.25Ag2MoO4 have been measured by differential scanning calorimetry (DSC), X-ray diffraction (XRD), and 109Ag solid-state nuclear magnetic resonance (NMR) both in the glassy and supercooled liquid states. In the glassy state, two Ag+ populations exist with very different mobilities which are related to different co-ordination spheres. Above the glass transition temperature, the sample undergoes phase separation and gives β-AgI and 2AgI–Ag2MoO4 (2:1) crystals. Cations dynamics decrease and chemical shift anisotropy structures arise. The ionic conduction is based on Ag+ sites with mixed co-ordination, and no evidence of AgI clustering is found." @default.
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• W2071566291 date "1998-07-01" @default.
• W2071566291 modified "2023-10-10" @default.
• W2071566291 title "Ion dynamics and devitrification in 0.75AgI–0.25Ag2MoO4 fast ion conducting glass: an XRD, DSC and 109Ag NMR study" @default.
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• W2071566291 doi "https://doi.org/10.1016/s0022-3093(98)00428-1" @default.
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