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- W2071571199 abstract "Summary: We have prepared hexa-p-phenylene based rod-coil molecules with identical coil volume fractions, but different poly(propylene oxide) (PPO) coil architectures (linear versus dibranched), and investigated their self-assembling behavior in the solid state by small angle X-ray scattering (SAXS) and transmission electron microscopy (TEM) techniques. Rod-coil molecules with a linear PPO coil showed a honeycomb-like lamellar assembly of rod segments with hexagonally arrayed PPO coil perforations. In contrast, the rod-coil molecules with dibranched PPO coils self-organized into rod bundles with a body centered tetragonal symmetry surrounded by a PPO coil matrix. These results demonstrate that the steric hindrance at the rod/coil interface arising from coil architectural variation is a dominant parameter governing supramolecular rod assembly in the rod-coil system. TEM images and schematic illustrations of the self-assembled structures of rod-coil molecules with linear (left) and dibranched (right) PPO coils, respectively." @default.
- W2071571199 created "2016-06-24" @default.
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- W2071571199 date "2006-10-02" @default.
- W2071571199 modified "2023-10-16" @default.
- W2071571199 title "Chain Architecture Dependent 3-Dimensional Supramolecular Assembly of Rod-Coil Molecules with a Conjugated Hexa-p-phenylene Rod" @default.
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- W2071571199 doi "https://doi.org/10.1002/marc.200600445" @default.
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