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• W2071571457 abstract "Abstract Amine adducts of tert-butylthiolate gallium hydrides were synthesized for possible use as precursors to gallium sulfide films. Reactions of GaH3L (L=NMe3 or quinuclidine) with 1 or 2 equiv. of t-BuSH and GaH3−xClx(quin) with 1 or 2 equiv. of LiS-t-Bu produced mixtures of products. The complexes GaH(St-Bu)2(NMe3) and GaH2(St-Bu)(quin) were isolated as crystalline solids from the product mixtures and both were characterized by X-ray crystallography. In the solid state, GaH(St-Bu)2(NMe3) is best described as having a trigonal pyramidal geometry. The complexes Ga(St-Bu)3L (L=NMe3 or quinuclidine) were synthesized from GaH3L and a slight excess of t-BuSH." @default.
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• W2071571457 date "2001-08-01" @default.
• W2071571457 modified "2023-10-18" @default.
• W2071571457 title "Amine adducts of tert-butylthiolate gallium hydrides—synthetic and X-ray crystallographic studies" @default.
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• W2071571457 doi "https://doi.org/10.1016/s0277-5387(01)00845-2" @default.
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