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• W2071586142 abstract "The introduction of all-hydrocarbon i,i+3 staples into α-helical peptide scaffolds via ring-closing olefin metathesis (RCM) between two α-methyl,α-pentenylglycine residues incorporated at i and i+3 positions, which lie on the same face of the helix, has been investigated. The reactions were found to be highly dependent upon the side-chain stereochemistry of the amino acids undergoing RCM. The i,i+3 stapling system established here provides a potentially useful alternative to the well-established i,i+4 stapling system now in widespread use." @default.
• W2071586142 created "2016-06-24" @default.
• W2071586142 creator A5027055362 @default.
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• W2071586142 date "2010-06-07" @default.
• W2071586142 modified "2023-10-07" @default.
• W2071586142 title "Introduction of All-Hydrocarbon <i>i</i>,<i>i</i>+3 Staples into α-Helices via Ring-Closing Olefin Metathesis" @default.
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• W2071586142 doi "https://doi.org/10.1021/ol1010449" @default.
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