Matches in SemOpenAlex for { <https://semopenalex.org/work/W207162005> ?p ?o ?g. }
- W207162005 endingPage "10" @default.
- W207162005 startingPage "1" @default.
- W207162005 abstract "Catalytic cyclohexene epoxidation with iodosylbenzene by the following Mn-porphyrins bearing ortho substituents on a meso group: MnTTP, MnM2-OHPTTP(5-(2-hydroxyphenyl)-10,15,20-tritolylporphyrin) and MnM2-BrPTTP(5-(2-(3-bromo-1-propoxy)phenyl)-10,15,20-tritolylporphyrin), has been studied. The effect of dioxygen and imidazole axial ligand on the yields of epoxide and allylic oxidation products, i.e. alcohol and ketone, was investigated. It was observed that the product selectivity is strongly dependent on the distribution of the Im/MnP species (M, MIm and MIm2 obtained by spectrophotometric titrations). For MnTPP at Im/MnP=1 the best epoxide yield associated with the maximum MIm concentration was observed. The presence of the OH substituent produced a remarkable effect on the reactivity and catalytic properties of the porphyrin system, i.e. drastic reduction in allylic oxidation, slight increase on the epoxide yield, a decrease on the formation of the MnP/Im complexes and change of the reactivity of the Mn center with PhIO. These results are discussed in terms of a possible electronic interaction of the oxygen ortho substituent and the porphyrin ring." @default.
- W207162005 created "2016-06-24" @default.
- W207162005 creator A5022624414 @default.
- W207162005 creator A5075695813 @default.
- W207162005 creator A5082637091 @default.
- W207162005 date "2001-03-01" @default.
- W207162005 modified "2023-09-27" @default.
- W207162005 title "Manganeseporphyrin catalyzed cyclohexene epoxidation by iodosylbenzene" @default.
- W207162005 cites W1582030318 @default.
- W207162005 cites W1583977177 @default.
- W207162005 cites W1971446668 @default.
- W207162005 cites W1975678577 @default.
- W207162005 cites W1982596941 @default.
- W207162005 cites W1983791889 @default.
- W207162005 cites W1992413871 @default.
- W207162005 cites W1992939879 @default.
- W207162005 cites W1995877087 @default.
- W207162005 cites W2004741498 @default.
- W207162005 cites W2010862253 @default.
- W207162005 cites W2015835975 @default.
- W207162005 cites W2022988636 @default.
- W207162005 cites W2027181699 @default.
- W207162005 cites W2027557303 @default.
- W207162005 cites W2055846807 @default.
- W207162005 cites W2056522495 @default.
- W207162005 cites W2064553003 @default.
- W207162005 cites W2068177962 @default.
- W207162005 cites W2071449912 @default.
- W207162005 cites W2072142578 @default.
- W207162005 cites W2073356400 @default.
- W207162005 cites W2073750177 @default.
- W207162005 cites W2075491748 @default.
- W207162005 cites W2088012925 @default.
- W207162005 cites W2089843457 @default.
- W207162005 cites W2090041248 @default.
- W207162005 cites W2090388453 @default.
- W207162005 cites W2092558206 @default.
- W207162005 cites W2094289644 @default.
- W207162005 cites W2143347142 @default.
- W207162005 cites W2334912119 @default.
- W207162005 cites W2896546755 @default.
- W207162005 cites W2951974708 @default.
- W207162005 cites W629624205 @default.
- W207162005 doi "https://doi.org/10.1016/s1381-1169(00)00446-5" @default.
- W207162005 hasPublicationYear "2001" @default.
- W207162005 type Work @default.
- W207162005 sameAs 207162005 @default.
- W207162005 citedByCount "47" @default.
- W207162005 countsByYear W2071620052012 @default.
- W207162005 countsByYear W2071620052014 @default.
- W207162005 countsByYear W2071620052015 @default.
- W207162005 countsByYear W2071620052016 @default.
- W207162005 countsByYear W2071620052017 @default.
- W207162005 countsByYear W2071620052018 @default.
- W207162005 countsByYear W2071620052019 @default.
- W207162005 countsByYear W2071620052021 @default.
- W207162005 countsByYear W2071620052023 @default.
- W207162005 crossrefType "journal-article" @default.
- W207162005 hasAuthorship W207162005A5022624414 @default.
- W207162005 hasAuthorship W207162005A5075695813 @default.
- W207162005 hasAuthorship W207162005A5082637091 @default.
- W207162005 hasConcept C116569031 @default.
- W207162005 hasConcept C118792377 @default.
- W207162005 hasConcept C120095180 @default.
- W207162005 hasConcept C134121241 @default.
- W207162005 hasConcept C142724271 @default.
- W207162005 hasConcept C155647269 @default.
- W207162005 hasConcept C161790260 @default.
- W207162005 hasConcept C170493617 @default.
- W207162005 hasConcept C178790620 @default.
- W207162005 hasConcept C184866935 @default.
- W207162005 hasConcept C185592680 @default.
- W207162005 hasConcept C191897082 @default.
- W207162005 hasConcept C192562407 @default.
- W207162005 hasConcept C204787440 @default.
- W207162005 hasConcept C2776910235 @default.
- W207162005 hasConcept C2776920199 @default.
- W207162005 hasConcept C2777738585 @default.
- W207162005 hasConcept C2778689049 @default.
- W207162005 hasConcept C2779480358 @default.
- W207162005 hasConcept C2779484182 @default.
- W207162005 hasConcept C2779879930 @default.
- W207162005 hasConcept C2780874372 @default.
- W207162005 hasConcept C55493867 @default.
- W207162005 hasConcept C71240020 @default.
- W207162005 hasConcept C71924100 @default.
- W207162005 hasConcept C75473681 @default.
- W207162005 hasConceptScore W207162005C116569031 @default.
- W207162005 hasConceptScore W207162005C118792377 @default.
- W207162005 hasConceptScore W207162005C120095180 @default.
- W207162005 hasConceptScore W207162005C134121241 @default.
- W207162005 hasConceptScore W207162005C142724271 @default.
- W207162005 hasConceptScore W207162005C155647269 @default.
- W207162005 hasConceptScore W207162005C161790260 @default.
- W207162005 hasConceptScore W207162005C170493617 @default.
- W207162005 hasConceptScore W207162005C178790620 @default.
- W207162005 hasConceptScore W207162005C184866935 @default.
- W207162005 hasConceptScore W207162005C185592680 @default.