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- W2071620122 abstract "Partial exchange of the alkali metal ions for tetraalkylammonium cations of Rb3P7 and Cs3P11 in liquid ammonia results in the formation of [(CH3)4N]2RbP7(NH3) (1) and [(C2H5)4N]Cs2P11 (2). The crystal structures reveal the existence of one-dimensional [RbP7]2− chains in the former and two-dimensional [Cs2P11]− layers in the latter compound. The nortricyclane cage in 1 is distorted by one-sided coordination to the Rb ions in a manner that can be related to the valence tautomerism of the free P73− anion." @default.
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- W2071620122 date "1996-02-01" @default.
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- W2071620122 title "Alkali Metal Polyphosphides in Low Dimensions: Synthesis and Structure of [(CH <sub>3</sub> ) <sub>4</sub> N] <sub>2</sub> RbP <sub>7</sub> (NH <sub>3</sub> ) and [(C <sub>2</sub> H <sub>5</sub> ) <sub>4</sub> N]Cs <sub>2</sub> P <sub>11</sub>" @default.
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- W2071620122 doi "https://doi.org/10.1002/cber.19961290208" @default.
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