Matches in SemOpenAlex for { <https://semopenalex.org/work/W2071692267> ?p ?o ?g. }
Showing items 1 to 93 of
93
with 100 items per page.
- W2071692267 endingPage "10350" @default.
- W2071692267 startingPage "10340" @default.
- W2071692267 abstract "A related series of flexible and rigid C16- and C20-tetraether bolaamphiphiles containing two phosphocholine headgroups and either acyclic or macrocyclic side chains were synthesized starting from 2-phenyl-5-hydroxy-1,3-dioxane. Two different synthetic strategies were developed. The saturated acyclic and macrocyclic derivatives were prepared via olefin metathesis using a [(PCy3)2RuCHPh]Cl2 catalyst in the key homocoupling step. Acyclic and macrocyclic tetrayne analogues were prepared using high-temperature Glaser oxidation in the dimerization step. Monolayer experiments of these materials suggest that the flexible lipids assume a U-shaped conformation; however, the rigid derivatives appear to adopt an upright conformation at the air−water interface in agreement with the predictions of Diamant and Andelman. We infer from these studies that bolaamphiphiles bearing macrocyclic transmembrane C20 hydrophobic chains are sufficiently rigid that they sacrifice contact of a headgroup with the aqueous subphase to accommodate an extended molecular orientation at the air−water interface." @default.
- W2071692267 created "2016-06-24" @default.
- W2071692267 creator A5014054020 @default.
- W2071692267 creator A5052262788 @default.
- W2071692267 date "2000-11-28" @default.
- W2071692267 modified "2023-09-24" @default.
- W2071692267 title "Novel Flexible and Rigid Tetraether Acyclic and Macrocyclic Bisphosphocholines: Synthesis and Monolayer Properties" @default.
- W2071692267 cites W1965198385 @default.
- W2071692267 cites W1966005197 @default.
- W2071692267 cites W1978447022 @default.
- W2071692267 cites W1979667894 @default.
- W2071692267 cites W1980293778 @default.
- W2071692267 cites W1983120955 @default.
- W2071692267 cites W1983855530 @default.
- W2071692267 cites W1989741246 @default.
- W2071692267 cites W1994051601 @default.
- W2071692267 cites W1999452060 @default.
- W2071692267 cites W2019979303 @default.
- W2071692267 cites W2028618864 @default.
- W2071692267 cites W2030186283 @default.
- W2071692267 cites W2035556774 @default.
- W2071692267 cites W2039070915 @default.
- W2071692267 cites W2044827833 @default.
- W2071692267 cites W2048776426 @default.
- W2071692267 cites W2053873800 @default.
- W2071692267 cites W2055553028 @default.
- W2071692267 cites W2070636386 @default.
- W2071692267 cites W2080123807 @default.
- W2071692267 cites W2093742493 @default.
- W2071692267 cites W2119578867 @default.
- W2071692267 cites W2139640905 @default.
- W2071692267 cites W2142495231 @default.
- W2071692267 cites W2350683599 @default.
- W2071692267 doi "https://doi.org/10.1021/la001104q" @default.
- W2071692267 hasPublicationYear "2000" @default.
- W2071692267 type Work @default.
- W2071692267 sameAs 2071692267 @default.
- W2071692267 citedByCount "47" @default.
- W2071692267 countsByYear W20716922672012 @default.
- W2071692267 countsByYear W20716922672013 @default.
- W2071692267 countsByYear W20716922672014 @default.
- W2071692267 countsByYear W20716922672016 @default.
- W2071692267 countsByYear W20716922672017 @default.
- W2071692267 countsByYear W20716922672018 @default.
- W2071692267 countsByYear W20716922672019 @default.
- W2071692267 countsByYear W20716922672021 @default.
- W2071692267 countsByYear W20716922672023 @default.
- W2071692267 crossrefType "journal-article" @default.
- W2071692267 hasAuthorship W2071692267A5014054020 @default.
- W2071692267 hasAuthorship W2071692267A5052262788 @default.
- W2071692267 hasConcept C153914509 @default.
- W2071692267 hasConcept C178790620 @default.
- W2071692267 hasConcept C184651966 @default.
- W2071692267 hasConcept C185592680 @default.
- W2071692267 hasConcept C2994504213 @default.
- W2071692267 hasConcept C44228677 @default.
- W2071692267 hasConcept C521977710 @default.
- W2071692267 hasConcept C55493867 @default.
- W2071692267 hasConcept C7070889 @default.
- W2071692267 hasConcept C71240020 @default.
- W2071692267 hasConcept C8010536 @default.
- W2071692267 hasConceptScore W2071692267C153914509 @default.
- W2071692267 hasConceptScore W2071692267C178790620 @default.
- W2071692267 hasConceptScore W2071692267C184651966 @default.
- W2071692267 hasConceptScore W2071692267C185592680 @default.
- W2071692267 hasConceptScore W2071692267C2994504213 @default.
- W2071692267 hasConceptScore W2071692267C44228677 @default.
- W2071692267 hasConceptScore W2071692267C521977710 @default.
- W2071692267 hasConceptScore W2071692267C55493867 @default.
- W2071692267 hasConceptScore W2071692267C7070889 @default.
- W2071692267 hasConceptScore W2071692267C71240020 @default.
- W2071692267 hasConceptScore W2071692267C8010536 @default.
- W2071692267 hasIssue "26" @default.
- W2071692267 hasLocation W20716922671 @default.
- W2071692267 hasOpenAccess W2071692267 @default.
- W2071692267 hasPrimaryLocation W20716922671 @default.
- W2071692267 hasRelatedWork W1970353612 @default.
- W2071692267 hasRelatedWork W1986856861 @default.
- W2071692267 hasRelatedWork W2009823598 @default.
- W2071692267 hasRelatedWork W2056155834 @default.
- W2071692267 hasRelatedWork W2159524486 @default.
- W2071692267 hasRelatedWork W2334674240 @default.
- W2071692267 hasRelatedWork W2949080510 @default.
- W2071692267 hasRelatedWork W2951261188 @default.
- W2071692267 hasRelatedWork W2951280107 @default.
- W2071692267 hasRelatedWork W2951314393 @default.
- W2071692267 hasVolume "16" @default.
- W2071692267 isParatext "false" @default.
- W2071692267 isRetracted "false" @default.
- W2071692267 magId "2071692267" @default.
- W2071692267 workType "article" @default.