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- W2071704927 abstract "The reaction of 9,10-dimethylanthracene with FcH-AlCl3-Al in decalin at 130°C gave stereospecifically the η6-cis-(endo-9,10-dihydro)-9,10-dimethylanthracene-η5-cyclopentadienyliron cation (III), the H atoms at C-9,10 being introduced from the same side of the ring system as the CpFe group. When cis-9,10-dihydro-9,10-dimethylanthracene was used as the arene in the ligand exchange reaction, the CpFe moiety could complex from either direction and gave a mixture of the cis-(endo-9,10-dihydro) cation III and the cis-(exo-9,10-dihydro) cation IV. The stereochemical results suggested a direct role for the Fe atom in the hydrogenations observed in such ligand exchange reactions." @default.
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- W2071704927 date "1977-04-01" @default.
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- W2071704927 title "The stereochemistry of the hydrogenation during ligand exchange reactions between ferrocene and 9,10-dimethylanthracene" @default.
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- W2071704927 doi "https://doi.org/10.1016/s0022-328x(00)93235-2" @default.
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