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- W2071723390 abstract "The degradative processes and dismutation reactions of haloalkanes of the CHCl 3− n F n -series during the activation of a γ-Al 2 O 3 -catalyst were studied. The following main degradative products were obtained: carbon monoxide, hydrogen chloride, water and different Al-F-species on the surface of the solid. Competitive reactions were separated by changing the experimental conditions. The layer of different Al-F-species on the surface, which is formed during the activation, is more active for catalyzing dismutation reactions than the pure hydroxide and oxide surface. The results are explained in connection with thermodynamic considerations. Advantages and disadvantages of the two following models of the degradation mechanism are discussed:" @default.
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- W2071723390 date "1992-08-01" @default.
- W2071723390 modified "2023-09-27" @default.
- W2071723390 title "Degradative and dismutation reactions of hydrofluorochlorocarbons on modified γ-aluminium oxide catalysts" @default.
- W2071723390 doi "https://doi.org/10.1016/s0022-1139(00)80774-5" @default.
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