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- W2071723994 abstract "Contactless electrostatic force microscopy (EFM) and dielectric force microscopy (DFM) are demonstrated to be very powerful tools of characterizing the electronic properties of individual single-walled carbon nanotubes (SWCNTs). Taking the advantages of the tools, we confirm that the metallicity of metallic SWCNTs can be largely preserved upon dichlorocarbene functionalization ([2 + 1] cycloaddition) in comparison with the SWCNTs subject to the Prato reaction ([2 + 3] cycloaddition). This work demonstrates the distinct difference between sp2 rehybridized and sp3 rehybridized covalent configurations on their influences to electronic properties of metallic SWCNTs and supports the hypothesis that [2 + 1] cycloaddition could recover the sp2 hybridization on the sidewall of metallic SWCNTs and preserve the intrinsic electronic properties of SWCNTs." @default.
- W2071723994 created "2016-06-24" @default.
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- W2071723994 date "2013-11-08" @default.
- W2071723994 modified "2023-10-02" @default.
- W2071723994 title "Covalently Functionalized Metallic Single-Walled Carbon Nanotubes Studied Using Electrostatic Force Microscopy and Dielectric Force Microscopy" @default.
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- W2071723994 doi "https://doi.org/10.1021/jp4076178" @default.
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