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- W2071762016 abstract "Abstract A new approach to the analysis of the U-shaped dependence of 29 Si NMR chemical shifts on the sum of group electronegativities of ligands, based on a proper account of the presence of the silicon core AO of the same symmetry as the silicon valence 3p AO is presented. A new dependence between λ Si =〈 r −3 〉 3p and the valence AO populations has been established. 29 Si NMR chemical shift calculations for organosilicon compounds using the FPT INDO-CS method are in good agreement with experimental data." @default.
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- W2071762016 date "1988-11-01" @default.
- W2071762016 modified "2023-09-27" @default.
- W2071762016 title "29Si NMR: A new approach to the analysis of chemical shift variations" @default.
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- W2071762016 doi "https://doi.org/10.1016/0009-2614(88)87325-1" @default.
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