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- W2071773180 abstract "New mononuclear bis(alkyne) derivatives of functionalised titanocene [Ti(η5-C5H4R)2(CCBut)2] (R = PPh2 1, Ph2PO 7 or Ph2PS 8) have been isolated by reaction of [Ti(η5-C5H4R)2Cl2] (R = PPh2, Ph2PO or Ph2PS) and LiCCBut in diethyl ether. The reactions of the former species with (CuCl)n and [Mo(CO)4(nbd)] have been investigated. Novel heterobi- [LnM(µ-η5∶κP-C5H4PPh2)2Ti(µ-η2-CCBut)2] [MLn = CuCl 4 or Mo(CO)4 5], [{η5-C5H4P(E)Ph2}2Ti(µ-η2-CCBut)2CuCl] (E = O 9 or S 10) and heterotri-nuclear complexes [LnM(µ-η5∶κP-C5H4PPh2)2Ti(µ-η2-CCBut)2CuCl] [MLn= CuCl 2 or Mo(CO)4 6] have been synthesized. The crystal structure of compound 2 has been solved." @default.
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- W2071773180 date "1999-01-01" @default.
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- W2071773180 title "Co-ordinative ability of the new compounds [Ti(η5-C5H4R)2(CCBut)2] (R = PPh2, Ph2PO or Ph2PS) as precursors in the synthesis of heterodi- and heterotri-nuclear species. Crystal structure of [ClCu(μ-η5∶κP-C5H4PPh2)2Ti(μ-η2-CCBut)2CuCl]" @default.
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- W2071773180 doi "https://doi.org/10.1039/a807905f" @default.
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