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• W2071794166 abstract "The behavior of two holes in a phthalocyanine (2 + 2) tetramer which consists of two bis (phthalocyaninato) lutetium radicals is studied by absorption, MCD, ESR spectra. The dimer, one of whose phthalocyanine rings is peripherally substituted by four 15-crown-5 rings, forms a (2 + 2) tetramer in the presence of K+ ions in solution. All major absorption bands except the lowest energy band are blue-shifted with the tetramer formation. The (2 + 2) tetramer preserves the near-IR band that is a characteristic of the dimer radical, and shows a triplet ESR spectrum. The experimental results indicate that the tetramer is a biradical." @default.
• W2071794166 created "2016-06-24" @default.
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• W2071794166 date "1993-03-01" @default.
• W2071794166 modified "2023-10-18" @default.
• W2071794166 title "Biradical state in phthalocyanine (2 + 2) tetramer composed of two bis (phthalocyaninato) lutetium radicals" @default.
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• W2071794166 doi "https://doi.org/10.1016/0009-2614(93)85294-x" @default.
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